SAFETY DATA SHEET [1907/2006/EC] Article 31 Version V 4.00 dated 03.03.2008 Seite 1 von 10 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 1.1 Superflex C dated 02.09.2004replaces Version V 3.00dated 03.03.2008Version V 4.00 Product No.: 5032008 Sealant preparation for multiple application. 1.2 Use of the Substance/Preparation MSDS-History: BRANDNAME: 1.3 Superflex C 1.4 Phone-No.: 01254 265642 Telefax-No.: 01254 692483 Emergency Call: Supplier: AB Sealants Northern Ltd E-Mail: absealantsnorthern@talktalk.net Homepage: 2. HAZARD IDENTIFICATION 2.1 Hazards to man: The contact with the product is weakly irritating to the eyes and the skin. Product vapours and/or product dusts in high concentration irritating to the respiratory system and/or the mucous membranes. 2.2 Hazards to environment: In case of strict observance of appropriate disposal methods [see section 13] the product presents no special risk to the environment. Water Hazard Classification [Germany]: slightly water hazardous [WGK 1]. 2.3 Adverse physico-chemical effects: The product is combustible. Liberation of dangerous vapours/sprays [see section 10] during processing/use of the product in contact with water/humidity: 2-butanone oxime [CAS 96-29-7] 2.4 Other hazards: The product may stick to the skin [after dryness]. Information given herein is to the best of our knowledge and is only related to the product as delivered in order to give a complete review of safety aspects accurate as of the date indicated. All data given are never meant to guarantee product properties. It is the sole responsibility of the user to take all precautions required in handling the product. SAFETY DATA SHEET [1907/2006/EC] Article 31 Version V 4.00 dated 03.03.2008 Seite 2 von 10 BRANDNAME: Superflex C Supplier: AB Sealants Northern Ltd Address: Unit 4, Forrest Street, Blackburn, Lancashire, BB1 3BB 3. INFORMATION ON COMPOSITION Preparation/formulation based on the following components: Siloxanes - curing agent [type oximesilane] - pigment dyestuffs - inert additives. Total content curing agents [§ 3.1]: < 5%. Only type OX 3456.1 contains in very low concentration: fungicides [CAS: 10605-21-7] [see section 4.6]. 3.1 The Product Contains the Following Relevant Components: (1) methyltris(methylisobutylketoxime)silane (2) butan-2-one O,O',O''-(methylsilylidyne)trioxime (3) butan-2-one O,O',O''-(vinylsilylidyne)trioxime 3.2 Characterization of Components listed in Section 3.1 [ for Exposure Limits see Section 8.1 ] CAS EEC-No Index No. Warnings R-Phrases (1) 37859-57-7 423-580-0 Xn 48/22-53 (2) 22984-54-9 245-366-4 Xn 21-36-43 (3) 2224-33-1 218-747-8 Xi 38-41-43 3.3 CMT-Categorization of Components Listed in Section 3.1 EEC Category Carc Muta RF RE EEC Guideline (1)nc nc nc nc (2)nc nc nc nc (3)nc nc nc nc SAFETY DATA SHEET [1907/2006/EC] Article 31 Version V 4.00 dated 03.03.2008 Seite 3 von 10 BRANDNAME: Superflex C Supplier: AB Sealants Northern Ltd 4. FIRST AID MEASURES General measures are not necessary. After separating the eyelids immediately flush eyes thoroughly with plenty of water In case eye irritation persists, consult an oculist. Remove contaminated clothing and shoes. Wash affected skin thoroughly and lasting with plenty of soap and water. In case of persisting irritation call in a physician. Where possible show the physician container or label. Guide affected person to medical treatment or call for medical assistance. Guide affected person to fresh air. Ease clothes. Keep free the respiratory ways. In case inconvenience persists seek medical advice. Show the physician container or label. 4.1 General Instructions 4.2 In Case of Eye Contact 4.3 In Case of Skin Contact 4.4 In Case of Ingestion 4.5 In Case of Inhalation 4.6 Notes to the Physician There is no specific information available about the product. Treat affected person according to symptoms developing. Only type OX 3456.1 contains fungicides in very low concentration: carbendazim [< 0.1%]. 5. FIRE FIGHTING MEASURES Carbon dioxide, powder and foam extinguisher, water spray. The product is commercially distributed only in small containers. The main fire hazard is the inflammability of the packaging material. The product is combustible. Possible formation of explosible mixtures with air. Properties of combustion gases/vapours: toxic - corrosive. Cool containers exposed to the fire with water spray. Protective equipment in the event of fire: self-contained breathing apparatus and suitable chemical protection clothing. Prevent fire-fighting water from entering surface water or groundwater. Collect contaminated extinguishing water and dispose off according to the local restrictions [see section 13]. Suitable Extinguishing Media: Not to be Used for Safety Reasons: Specific Exposure Hazards Arising from the Substance or its Combustion Products: Specific Protective Equipment and Measures Required for Fire-Fighting: Water jet. 6. ACCIDENTAL RELEASE MEASURES Person-related precautionary measures: Wear suitable protective equipment [see section 8.3]. Do not inhale vapours/aerosols. Avoid contact with substance. General precautionary measures: Secure undammaged small containers [tins, cartouches, tubes] in a well protected place. In case of big spill caused by dammaged small containers: Mark out area - warn out danger. Ensure supply of fresh air in enclosed rooms. Close all drains. Keep away substances to be avoided [see section 10]. Contain the spillage by bunding with universal binder and/or sand. SAFETY DATA SHEET [1907/2006/EC] Article 31 Version V 4.00 dated 03.03.2008 Seite 4 von 10 BRANDNAME: Superflex C Supplier: AB Sealants Northern Ltd Storage7.2 7. HANDLING AND STORAGE 7.1 Handling refer to technical data sheet. 7.3 Specific Uses 6. ACCIDENTAL RELEASE MEASURES [CONTINUED] Store product only in tightly closed original container in a cool, well-ventilated place. Protect the product against frost and influence of weather factors - humidity and water. Storage temperature from < 40 °C in order to maintain the product quality. Use product very soon once original packaging is opened. Specific design for storage rooms: dry - frost protected - safe. Comply with national regulatory directives: Storage of water hazardous substances. Precautions for safe handling: Use product only in well ventilated areas/workplaces. Do not inhale vapours/aerosols. Do not smoke during work. Advice on technical measures: For non-professional user: none. Further specific requirements: Process product away from substances to be avoided [see section 10]. Avoid any uncontrolled contact with humidity/water. Provide at the working place: eyewash fountains. Comply with the instructions for use [refer to technical data sheet]. Procedures for cleaning/absorption: allow spilled viscous product to cure, then take up using spatula, broom, spade and/or Absorb spilled viscous product using universal binder and/or sand. Mob up spill in suitable container, forward material and container for disposal. Clean affected area with water and surfactant. Environmental-protection measures: In case of environmental pollution inform fire brigade or police. SAFETY DATA SHEET [1907/2006/EC] Article 31 Version V 4.00 dated 03.03.2008 Seite 5 von 10 BRANDNAME: Superflex C Supplier: AB Sealants Northern Ltd Address: Unit 4, Forrest Street, Blackburn, Lancashire, BB1 3BB 8. EXPOSURE CONTROL AND PERSONAL PROTECTIVE EQUIPMENT 8.1 Components with an Exposure Limitation a) Exposure Limits Related to the Product Source CAS Name TWA ml/m³ mg/m³ Cat. STEL ml/m³ mg/m³ Refer Notes b) Exposure Limits of Components as Listed in Section 3.1 An occupational exposure limit value has not yet been fixed for 2-butanone oxime. It is recommended to avoid any 8.2 Environmental Exposure Controls environmentally relevant limit values: no data available. SAFETY DATA SHEET [1907/2006/EC] Article 31 Version V 4.00 dated 03.03.2008 Seite 6 von 10 BRANDNAME: Superflex C Supplier: AB Sealants Northern Ltd Address: Unit 4, Forrest Street, Blackburn, Lancashire, BB1 3BB 8.3 Personal Hygiene and Personal Protective Equipment Respect the general regulations of industrial working hygiene as stated by the responsible professional association. Do not breathe product vapours released during product vulcanisation. When using do not eat, drink or smoke. Wash your hands after work. Respiratory: Respiratory protection is not necessary. Eye: Safety goggles with side-protection [not obligatory but recommended]. Hand: Impervious safety gloves [protection index 3 ; breakthrough time according to EN 374: > 60 min]. butyl rubber - plastic - PVC Body: working clothes. 9. PHYSICAL AND CHEMICAL PROPERTIES State: [at 20 °C] pasty Colour: varicoloured Odour: weak 9.1 Change in Physical State Point of Decomposition > 200 °C °C °C 9.2 Density (20 °C ) approx. 1.0 g/cm³ ( °C ) g/cm³ Bulk Density ( 20 °C )not applicable kg/m³ 9.3 Vapour Pressure ( 20 °C )< 1 hPa ( °C ) hPa 9.4 Viscosity ( 20 °C )pasty ( °C ) 9.5 Water Solubility (20 °C ) practically insoluble g/l Fat Solubility partly miscible with the commonly used organic solvents 9.6 pH-Value ( 20 °C ) not applicable (at g/l H2O) 9.7 Flashpointin closed cup > 140 °C DIN 51755 9.8 Auto-ignition temperatureapprox. 435 °C 9.9 Explosure Limits lower: -upper: -keine Angaben vorhanden The product is a non-oxidizing material [Directive 67/548/EEC, Annex A.16]. 9.10 Partition coefficient [n-octanol/water; log Pow] not applicable 9.11 Further Data VOC-Share: < 3% [Lit 1]. SAFETY DATA SHEET [1907/2006/EC] Article 31 Version V 4.00 dated 03.03.2008 Seite 7 von 10 BRANDNAME: Superflex C Supplier: AB Sealants Northern Ltd Address: Unit 4, Forrest Street, Blackburn, Lancashire, BB1 3BB 10. STABILITY AND REACTIVITY Conditions to Avoid: The product is stable by appropiate use at ambient temperatures. Products to Avoid: strong oxidizing agents [reaction]. strong acids [reaction]. water/humidity [liberation of 2-butanone oxime]. Hazardous Decomposition Products: Hazardous combustion gases and/or vapours: carbon monoxide and carbon dioxide - nitrogen oxides - silica. 11. TOXICOLOGICAL INFORMATION Prolonged/repeated contact with the product is weakly irritating to the eyes and the skin. The product is not irritating to the eyes and the skin of the rabbit. The product is not sensitising the skin of a guinea pig. [Results achieved with a product of very similar composition]. [Lit 1] 2-butanone oxime [CAS 96-29-7] [local tolerance] eyes/rabbit: [100 µl] severe [Lit 2]. [acute toxicity] LD(50)oral/ rat: 930 mg/kg [Lit 2]. LD(50)cutaneous/ rat: > 2000 mg/kg [Lit 2]. LC(50)inhalation/ rat: 50 g/m³ /4 h [Lit 2]. 12. ECOLOGICAL INFORMATION In case of strict observance of appropriate disposal methods [see section 13] the product presents no special risk to the environment. Water Hazard Classification [Germany]: slightly water hazardous [WGK 1]. The product is practically insoluble in water and readily forms deposits. The product is not readily biodegradable. The product has a low bioaccumulative potential. [Lit 1] Do not release the product in the environment. Decant and purify polluted waste water before its release into the drains. 2-butanone oxime [CAS 96-29-7] LC(50) pimephales promelas/ 96 h: 844 mg/l [Lit 3]. SAFETY DATA SHEET [1907/2006/EC] Article 31 Version V 4.00 dated 03.03.2008 Seite 8 von 10 BRANDNAME: Superflex C Supplier: AB Sealants Northern Ltd 13. DISPOSAL CONSIDERATIONS Allow substance/preparation to cure and dispose [landfilling - category: commercial wastes]. Allow substance/preparation to cure and dispose [landfilling - category: municipal wastes]. Separate different packaging material. Appropriate methods of disposal for container: Dispose empty small containers [tins, cartouches, tubes] - [landfilling - category: commercial wastes/landfilling - category: municipal wastes]. List of hazardous wast [Directive 75/442/EEC]: classification has to be carried out in own responsibility. [Recommendation]: 08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products) EEC Waste Code: EEC Waste Code: EEC Waste Code: 08 04 09 waste adhesives and sealants containing organic solvents or other dangerous substances 08 04 99 wastes not otherwise specified 14. TRANSPORT INFORMATION 14.1 Transport Regulations Road 14.2 Transport Regulations Sea 14.3 Transport Regulations Air UN-No.: 0000 RID/ADR: - Danger-Code: -Label: - Pack-Group: - Shipping Name: not a dangerous good Hazard caused by: Limited. Quantity: - UN-No.: 0000 IMO/IMDG-Class:- MFAG-No.: -EMS-No.: -MarPol: - Pack-Group: - ADNR: - Label: - Shipping Name: not a dangerous good Hazard caused by: Limited Quantity: Preparation/ formulation: not a dangerous good. 0000 ICAO/IATA-Class: Pack- Group: - UN-No.: Shipping Name: not a dangerous good Hazard caused by: Label: - --Passenger Aircraft/Quantity: Cargo Aircraft/Quantity: Limited. Quantity: - SAFETY DATA SHEET [1907/2006/EC] Article 31 Version V 4.00 dated 03.03.2008 Seite 9 von 10 BRANDNAME: Superflex C Supplier: AB Sealants Northern Ltd 15.1 REGULATORY INFORMATION Warning Sign(s): Labelling [Directives 67/548/EEC and 1999/45/EC]: not concerned. none none R-Phrase(s): S-Phrase(s): Additional labelling [Directives 67/548/EEC and 1999/45/EC]: Contains "2-butanone oxime". May produce an allergic reaction. Safety data sheet available for professional user on request. Preparation and/or components are listed in: European Inventory of Existing Commercial Chemical Substances Listing [EINECS/ELINCS] Water-Hazard Classification: WGK 1 [Lit 1]. Product Classification SAFETY DATA SHEET [1907/2006/EC] Article 31 Version V 4.00 dated 03.03.2008 Seite 10 von 10 BRANDNAME: Superflex C Supplier: AB Sealants Northern Ltd ADDITIONAL INFORMATION R21 - Harmful in contact with skin. R36 - Irritating to eyes. R38 - Irritating to skin. R41 - Risk of serious damage to eyes. R43 - May cause sensitization by skin contact. R48/22 - Harmful: danger of serious damage to health by prolonged exposure if swallowed. 16.3 R Phrases Referring to Headings 2 and 3 : [Lit 1]: Unpublished producer results. [Lit 2]: Registry of Toxic Effects of Chemical Substances, CD-ROM Silver Platter (1997). [Lit 3]: Literature Data. Abbreviations: nc: not classified. nyc: not yet classified. Adaption to Regulation EC 1907/2006 [Reach]. All sections are concerned. 16.2 The following Sections of the MSDS compared to Version dated 02.09.2004 has been revised: 16.1 References